It is important to understand that radioactive decay is entirely a random and unpredictable process. If we look at any one nucleus, it might decay in ten seconds or ten million years. There is no way of telling when the decay will happen, and there is certainly no way of speeding up the process. Remember that chemical reactions involve the outer shell electrons; radioactive decay involves the nucleus.
However
when we have many millions of millions of nuclei, we can apply statistical
models of probability.
The
rate of disintegration of any nuclide
at any time is directly proportional to the number of atoms left at the time:
This
is calculus notation for rate of change in number.
The
minus sign tells us that
N
decreases
as time increases.
There
is a constant of proportionality called the radioactive decay constant, which is given the physics code
l
(greek letter ‘l’,
not to be confused with wavelength), and has the units s^{1}.
So we can write:
The
radioactive decay constant is defined as the fraction of the total number of nuclei present that decays per unit
time, provided that the time interval is small.
For nuclides with relatively long halflives, the decay constant will
have units “per second”. However
some very unstable nuclides decay in microseconds, so the decay constant would
have to be “per nanosecond”.
Example
0.25 kg radon226 emits alpha particles at a measured rate of 9 × 10^{12} s^{1}. What is the decay constant of radium? (No of atoms in a mole = 6 × 10^{23}) 
Work out the number of particles:
1 mole of radon atoms has a mass of 0.226 kg.
0.250 × 6 × 10^{23} = 6.64 × 10^{23}
atoms 0.226 
We
know that the rate of decay is 9 × 10^{12} s^{1}. So we use
DN/Dt
= lN
 9 × 10^{12} s^{1} = l
× 6.64 × 10^{23}
l
= 1.36 × 10^{11} s^{1} (The minus sign indicates a decay) 
The unit Becquerel (Bq) is often used. 1 Bq = 1 count per second.
Question 1 
A sample of living material contains carbon 14 with an activity of 260 Bq kg^{1}. What is the decay constant? (The fraction that is made of carbon14 is 1.4 × 10^{12}) 
Over longer periods of time, the relationship above does not hold. It can be shown by calculus methods (which you are not expected to know), that the decay follows the relationship:
[N
– no of nuclei;
N_{0} – original number of nuclei;
e
– exponential number, 2.718…;
l  decay constant (s^{1});
t
– time (s)]
This relationship is described as an exponential decay and the graph looks like this:
We
should note the following:
The
rate of decay represents the number
of atoms remaining. So we
can use this graph for representation of the count rate, or ionisation
current.
The
rate of decay is the number of disintegrations
per second, or the activity.
It is measured in Becquerels (Bq).
1
Bq = 1 disintegration per second.
Notice
that the horizontal axis is calibrated in periods of time in which the decay
goes from an initial value to half that value.
This period is called the
halflife.
The formal definition of halflife is the time taken for the activity of
a sample to decrease to half some initial value.
After 1 half life the activity is 50 %, between 1 and 2 half lives it
falls from 50 % to 25 % and so on. If
we have a whole number of halflives, we can do an iterative calculation of the
fraction remaining, i.e. ½, ¼, 1/8, etc.
We
can relate the halflife to the decay constant:
By definition
The formula is N = N_{0}e^{}^{lt}. Rearranging gives us
T_{1/2} (pronounced "Thalf") is the physics code for halflife.
This
will work for any units of time, although we need to be consistent.
To
work with these relationships, you must be familiar with the concept of logarithms
(a way of expressing a number as a power of 10 or e).
You will see logarithms expressed as ‘lg’ or log_{10}, which
means log to the base 10, or ‘ln’ or log_{e}, log to the base
e.
The number
e is the exponential number, 2.718...
The latter are known as natural
logarithms, which are at the heart of exponential functions.
Example
A
radiographer has calculated that a patient is to be injected with 1
´ 10^{18} atoms of iodine 131 to
monitor thyroid activity. The
halflife is 8 days. Calculate:
(a)
the
radioactive decay constant
(b)
the
initial activity
(c)
the
number of undecayed atoms of iodine 131 after 24 days. (d) The total activity after 3 days. 
(a)
We need to use
T1/2
= 0.693 l
we
need to convert the 8 days into seconds.
Þ l = 0.693 _ = 1.00 ´ 10^{6} s^{1}^{ } 8 ´ 86400 
(b)
Use
DN
= 
lN =
1.00
´ 10^{6} s^{1}
´ 1
´
10^{18} = 1
´ 10^{12}
Bq Dt 
(c) 24 days is 3 halflives. Therefore
the number atoms remaining undecayed is 1/8 of the original.

(d)
3 is not so easy. We use
A
= A_{0}e^{}^{lt}
Þ
A = 1
´
10^{12} Bq
´ e^{(1.00
}
^{´}^{
106 s1 }
^{´}^{
3 }
^{´}^{
86400s)}
Þ
A = 1
´
10^{12} Bq
´ e^{(0.2592)} = 1 ´ 10^{12} Bq ´ 0.772 = 7.72 ´ 10^{11} Bq. 
[Alternative method] If you are not so confident in the use of the natural logarithm, you can work out the number of halflives a particular time gives. In this case 3 days = 3/8 of a half life.
Activity
= 1 ´ 10^{12}
´ 1/2^{3/8} = 1
´ 10^{12}
´ 1/1.30 = 7.7
´
10^{11} Bq
This is a perfectly valid alternative approach.
What is the half life of radon226? l = 1.36 × 10^{11} s^{1} 
The halflife has important implications for the storage of radioactive waste. Radioactive waste is some of the nastiest muck known to man, so it has to be stored carefully. Isotopes with a short halflife have intense activities, whereas those with a long halflife have lower activities, but it takes much longer for the activity to decay to a reasonable level. Either way, it’s not very nice.
Even
when there have been several halflives, there remains quite a considerable
activity. If in our example above
the activity had decayed to 1/1000^{th} of its original value, we would
still have 10^{9} disintegrations per second, which is quite a lot.
Another
use of the decay equations is in
radioactive
dating. Isotopes used are
carbon14, rubidium87, and hydrogen 3.
Question 3 
Strontium90 is a beta emitter. It is one of the radionuclides found in the fall out from an atomic bomb explosion. It can be absorbed into the bone. It emits beta particles and has a half life of 28 years. What is the time needed for the activity to fall to 5 % of the original? 

Question 4 
A
GM tube placed close to a radium source gives an initial average corrected count
rate of 334 s^{1}
(a)
The GM tube detects 10 % of the radiation. What is the initial activity?
(b)
Initially there were 1.5
´
10^{9} nuclei in the sample. What
is the decay constant? (c) What is the half life of the radium in days? 
Radioactive Dating
Carbon14 has a halflife of 5700 years. It decays by beta minus decay by this equation:
Carbon14 is made by the collision of an energetic neutron with a nitrogen nucleus, which results in the ejection of a proton. The energetic neutron is formed by cosmic ray activity. Therefore carbon14 is being made all the time. The rate of decay is balanced by the rate of formation, so the amount of carbon14 remains almost constant.
The proportion of carbon14 in living material is very low. For each gram of carbon, the countrate is about 140 min^{1}, 2.33 Bq. The count rate is therefore 2300 Bq kg^{1}. This is the reference point we use for 100 % activity.
If we know the activity of the sample, A, and the reference activity, A0, we can use the equation:
We can take natural logs to give us:
And this rearranges to:
lt = ln A  ln A_{0}
Since ln A_{0} is bigger than ln A, the right hand side of the equation is negative. The left hand side is negative, so the two negative signs cancel. This ensures that the time is positive. We can only go forward in time.
To work out the decay constant, we need to use the equation:
In this case the half life is 5700 years, which we have to convert to seconds. You do know how to do this, don't you?
Worked example In an archaeological dig, remains are found of a warrior who was buried using a wooden boat for a coffin. A 0.50 gram sample of the boat is found to have an activity of 3800 counts per hour. What is the age of the boat? The activity of carbon14 in living material is 2300 Bq kg1 and the halflife of carbon14 is 5700 years. 
Answer Find out the activity of the sample in Becquerel. A = 3800 ÷ 3600 = 1.056 Bq
Convert this to activity per unit mass.
A = 1.056 ÷ 0.5 × 10^{3} = 2111 Bq kg^{1}
Now we need to work out the decay constant. l = 0.693 ÷ (5700 × 365 × 24 × 3600) = 3.86 × 10^{12} s^{1}
Now use: lt = ln A  ln A_{0}
3.86 × 10^{12} ^{ }× t = ln (2111)  ln (2300)
3.86 × 10^{12} ^{ }× t =7.655  7.741 = 0.0857 Notice that the minus signs cancel: t = 0.0857 ÷ 3.86 × 10^{12} = 2.2 × 10^{10} s (700 years)
Normally you would leave your answer in seconds. The answer is given to 2 significant figures as the "activity in living material" data item is to 2 significant figures. 
The calculation above assumes that the level of carbon14 is the same in the year 1300 as it is now. If the cosmic ray activity were less then, the amount of carbon 14 would be reduced. The warrior's remains would be more recent.
Rock Dating
Carbon14 dating is only useful for objects under about 50000 years old. It's no good for dating rocks. The isotope potassium40 is useful. There are two modes of decay for potassium40:
Normal beta minus decay;
Electron Capture.
For beta minus, the decay is:
The half life for this is about 1250 million years.
For electron capture, the electron is captured from the inner shell:
About 1 in 8 decays is of the latter type. So out of 9 potassium40 atoms, 8 will decay to calcium, while 1 decays to argon. The problem with the decay to calcium is that calcium is as common as muck, so we wouldn't be able to tell which calcium atom came from the potassium decay, and which came from other sources.
However, Argon is an inert gas, and does not react with any crystals. Argon atoms remain trapped in the rock, so if we knew how many argon atoms there were, we could work out how many potassium atoms had decayed. So if we counted 12 × 10^{6} argon atoms, we could say that these resulted from 108 × 10^{6} potassium 40 atoms. So if we have 500 × 10^{6} potassium 40 atoms left, we can say that we would have started off with 108 × 10^{6} + 500 × 10^{6} = 608 × 10^{6} atoms.
Question 5 
If potassium40 has a halflife of 1250 million years, what is the age of the sample of rock discussed in the paragraph above? 
Summary
Radioactive
decays are random.
Rate
of decay depends on the number of atoms left
The
probability of any one nucleus decaying in any one second is the decay
constant
Decay
constant is given the code
l
DN
= lN
Dt
Over
a longer period of time, decay is exponential.
N
= No e^{l}^{t}
Half
life is the time taken for ½ the remaining atoms to decay
T_{1/2}
= 0.693
l 